Optical Transition Energies for Carbon Nanotubes from Resonant Raman Spectroscopy: Environment and Temperature Effects

    C. Fantini1, A. Jorio1, M. Souza1, M. S. Strano2, M. S. Dresselhaus3, and M. A. Pimenta1

    • 1Departamento de Física, Universidade Federal de Minas Gerais, Belo Horizonte, MG, 30123-970 Brazil
    • 2Department of Chemical and Biomolecular Engineering, University of Illinois at Urbana/Champaign, Urbana, Illinois 61801, USA
    • 3Department of Physics and Department of Electrical Engineering and Computer Science, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139-4307, USA

    Phys. Rev. Lett. 93, 147406 – Published 29 September, 2004

    DOI: https://doi.org/10.1103/PhysRevLett.93.147406

    Abstract

    This Letter reports the laser energy dependence of the Stokes and anti-Stokes Raman spectra of carbon nanotubes dispersed in aqueous solution and within solid bundles, in the energy range 1.52–2.71 eV. The electronic transition energies (Eii) and the radial breathing mode frequencies (ωRBM) are obtained for 46 different (18 metallic and 28 semiconducting) nanotubes, and the (n,m) assignment is discussed based on the observation of geometrical patterns for Eii versus ωRBM graphs. Only the low energy component of the E11M value is observed from each metallic nanotube. For a given nanotube, the resonant window is broadened and down-shifted for single wall carbon nanotube (SWNT) bundles compared to SWNTs in solution, while by increasing the temperature, the E22S energies are redshifted for S1 [(2n+m)mod3=1] nanotubes and blueshifted for S2 [(2n+m)mod3=2] nanotubes.

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